具有良好疏冰稳定性的低界面韧性涂层制备工艺

Fabrication of low interfacial toughness coatings with excellent icephobic stability

  • 摘要: 针对风电叶片表面大面积防除冰难题,本文提出一种通过有机硅聚合物(PDMS)与氟碳树脂(FEVE)共混构建互穿聚合物网络(IPN)结构的低界面韧性疏冰涂层制备策略,系统研究了涂层组分及其质量分数对疏冰性能的影响规律,确定了最优组分参数,并对优化涂层的疏冰性能及长期稳定性进行了测试。结果表明,FEVE与PDMS的共混比例能够调控冰–涂层界面裂纹扩展行为与表面粗糙度,从而显著影响疏冰性能;通过对PDMS进行改性可进一步降低涂层界面韧性。当PDMS∶FEVE共混质量比为2∶1、外添硅油占PDMS质量的50%时,涂层表现出最优疏冰性能:恒定除冰力为28.98 N/cm,对应冰粘附强度为24.08 kPa,界面韧性低至0.076 J/m2。结冰–除冰循环与户外暴露试验证明,该涂层同时具备优异的机械稳定性与耐候性。本研究提出的IPN结构协同改性策略,为兼顾低界面韧性与高机械稳定性的疏冰涂层设计提供了可行思路,所制备的涂层在大面积防除冰工程应用中具有良好的前景。

     

    Abstract: To address the challenge of large-scale anti-icing and de-icing on wind turbine blade surfaces, this study proposes a fabrication strategy for low interfacial toughness ice-phobic coatings by blending polydimethylsiloxane (PDMS) with fluorocarbon resin (FEVE) to construct an interpenetrating polymer network (IPN) structure. The effects of coating composition and mass fraction on ice-phobic performance were systematically investigated, optimal compositional parameters were determined, and the ice-phobic performance along with long-term stability of the optimized coating was evaluated. The results indicate that the blending ratio of FEVE to PDMS regulates ice-coating interfacial crack propagation behavior and surface roughness, thereby significantly affecting ice-phobicity. Modification of PDMS further reduced the interfacial toughness of the coating. When the PDMS∶FEVE mass ratio was 2∶1 and the content of external silicone oil was 50wt% relative to PDMS, the coating exhibited optimal performance: a constant de-icing force of 28.98 N/cm, corresponding to an ice adhesion strength of 24.08 kPa, and an interfacial toughness as low as 0.076 J/m2. Ice accumulation-deicing cycles and outdoor exposure tests demonstrated that the coating possesses excellent mechanical stability and weather resistance. The IPN-based synergistic modification strategy proposed in this study provides a feasible approach for designing ice-phobic coatings that balance low interfacial toughness with high mechanical stability, showing promising application prospects for large-area anti-/de-icing engineering.

     

/

返回文章
返回