ZrC增强Inconel 690涂层的耐磨性与耐腐蚀性研究

Research on the wear and corrosion resistance of Inconel 690 coatings reinforced by ZrC

  • 摘要: 为提升Inconel 690涂层的性能以满足核电设施中反应堆压力容器内部构件及控制棒驱动机构的应用需求,本研究提出了一种引入ZrC作为陶瓷增强相来提高涂层硬度和耐磨性的策略。通过激光熔覆工艺在304不锈钢基板上沉积了不同ZrC含量的ZrC/Inconel 690涂层。根据显微组织表征及各项性能测试结果,ZrC的加入能够通过析出强化与细晶强化的协同作用,显著提升涂层的硬度与耐磨性。其中,添加60wt.% ZrC的ZrC/Inconel 690涂层表现出最优的硬度与耐磨性,性能优于广泛使用的Stellite6涂层。然而,过高的ZrC含量会增加电化学点蚀的位点,导致耐腐蚀性下降。综合各项性能与实际服役工况考虑,含40wt.% ZrC的ZrC/Inconel 690涂层展现出最优的综合性能:大幅提高的显微硬度,优于传统Stellite6涂层的高温耐磨性,且耐腐蚀性与之接近,是极具潜力的核电用涂层候选材料。

     

    Abstract: To enhance the performance of the Inconel 690 coating to meet the application requirements of internal components of reactor pressure vessels and control rod drive mechanisms in nuclear power facilities, this study proposed a strategy of introducing ZrC as a ceramic reinforcing phase to increase the hardness and wear resistance of the coating. Through the laser cladding process, ZrC/Inconel 690 coatings with different ZrC contents were deposited on a 304 stainless steel substrate. Based on the microstructure characterization and results of various performance tests, the addition of ZrC can significantly improve the hardness and wear resistance of the coating through the synergistic effects of precipitation strengthening and fine grain strengthening. Among them, the ZrC/Inconel 690 coating with 60wt.% ZrC exhibited the best hardness and wear resistance, and its performance was superior to that of the widely used Stellite 6 coating. However, excessive ZrC content would increase the electrochemical pitting sites, resulting in a decrease in corrosion resistance. Considering all the performance indicators and actual operational conditions, the ZrC/Inconel 690 coating containing 40wt.% ZrC demonstrated the optimal comprehensive performance: a significantly increased microhardness, superior high-temperature wear resistance to traditional Stellite6 coating and comparable corrosion resistance.

     

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