热模压辅助先驱体浸渍裂解制备Cf/SiC复合材料研究

FABRICATION OF Cf/SiC COMPOSITES VIA PRECURSOR INFILTRATION AND PYROLYSIS ASSISTED BY HOT-PRESSING

  • 摘要: 以聚碳硅烷为先驱体,采用热模压辅助先驱体浸渍裂解工艺制备3D-B Cf/SiC复合材料,研究了热模压辅助对3D-B Cf/SiC复合材料致密度和力学性能的影响。结果表明:先驱体浸渍裂解制备陶瓷基复合材料第一次浸渍后引入高温热模压工艺可以改善材料微观结构,显著提高材料的致密度和力学性能。其中1600℃,10MPa,1h下热模压辅助先驱体浸渍裂解6次制备的3D-B Cf/SiC复合材料的密度为1.79g/cm3,弯曲强度高达672MPa,断裂韧性达18.9MPa·m1/2,剪切强度接近50MPa,且具有较好的抗热震性和高温抗氧化性。

     

    Abstract: Three-dimensional braided carbon fiber reinforced silicon carbide(3D-B Cf/SiC) composites were fabricated via polycarbosilane (PCS) precursor infiltration and pyrolysis processing assisted by hot-pressing. The influences of hot-pressing processing on the densities and mechanical properties of 3D-B Cf/SiC composites were studied. The results showed that the densities and mechanical properties of the composites were enhanced greatly by using hot-pressing processing after the first precursor infiltration during the fabricating of Ceramic Matrix Composites. The density,flexural strength,fracture toughness and shear strength of the composites, which were hot-pressed at 1600℃ for 1hour with a pressure of 10MPa in the first pyrolysis cycle and treated subsequently with six times of PCS precursor infiltration and pyrolysis under atmospheric pressure, were 1.79 g/cm3,672MPa,18.9MPa·m1/2 and about 50MPa, respectively. The composites had good heat shock resistance and high temperature oxidation resistance.

     

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