湿热环境下柔性梁复合材料性能退化及涂层防护

Study on the Property Degradation and Coating Protection of GFRP Composites for Flexible Beams under Hygrothermal Conditions

  • 摘要: 针对湿热环境导致玻璃纤维增强环氧树脂复合材料(GFRP)力学性能下降的问题,研究透明弹性涂层的表面防护作用。以单向及混杂铺层GFRP为对象,在70℃、85% RH条件下开展吸湿、拉伸和拉-拉疲劳试验,采用SEM、FTIR和TGA表征湿热作用下材料微观形貌、化学结构和热稳定性变化,并比较HB与FAA判据下裸露/带涂层试样的力学响应,评价不同涂层厚度的防护效果。结果表明,单向GFRP平衡吸湿率约0.72%;随吸湿率增加,拉伸强度由1645 MPa降至1027 MPa,疲劳极限由约40%降至34%;HB与FAA判据下材料退化规律一致,涂层均可改善湿热下拉伸和疲劳性能;混杂铺层GFRP以0.2 mm涂层厚度综合效果较优。透明弹性涂层可有效改善GFRP湿热下力学性能退化,为柔性梁复合材料表面防护设计提供依据。

     

    Abstract: To address the degradation in the mechanical properties of glass fiber reinforced epoxy composites (GFRP) under hygrothermal environments, the surface protection effect of a transparent elastic coating was investigated. Unidirectional and hybrid lay-up GFRP were studied. Moisture absorption, tensile, and tension-tension fatigue tests were conducted at 70℃ and 85% RH. SEM, FTIR, and TGA were employed to characterize the changes in microstructure, chemical structure, and thermal stability induced by hygrothermal exposure. In addition, the mechanical responses of uncoated and coated specimens under the HB and FAA criteria were compared, and the protective effect of different coating thicknesses was evaluated. The results showed that the equilibrium moisture absorption of unidirectional GFRP was about 0.72%. As the moisture absorption increased, the tensile strength decreased from 1645 MPa to 1027 MPa, and the fatigue limit decreased from about 40% to 34%. Similar degradation trends were observed under both the HB and FAA criteria, while the coating improved the tensile and fatigue properties under hygrothermal conditions. For hybrid lay-up GFRP, the coating with a thickness of 0.2 mm showed the best overall protective performance. The transparent elastic coating can effectively alleviate the hygrothermal degradation of GFRP and provide support for the surface protection design of flexible beam composite structures.

     

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