Fe3O4@TiO2-CNTs/BF复合材料的制备及电磁波吸收性能

Preparation and electromagnetic wave absorption properties of Fe3O4@TiO2-CNTs/BF composite materials

  • 摘要: 为了解决传统吸波材料难以兼顾宽频强吸收与轻质高强的痛点,本文通过引入玄武岩纤维作为结构骨架,以Fe3O4@TiO2-CNTs多级核壳结构为吸波核心,制备了Fe3O4@TiO2-CNTs/BF复合材料(FTC-O/BF)。通过XRD、SEM、TEM和Raman对其结构与形貌进行表征,并结合矢量网络分析仪测试与模拟计算分析其吸波性能。结果表明,当Fe3O4@TiO2∶CNTs为5∶1、厚度5 mm时,饱和磁化强度达26.8 emu·g−1,最低反射损耗可达-66.8 dB,有效带宽约2.2 GHz。基于该比例制备的FTC-O/BF复合材料,在16 mm厚度下具有双频段吸波特性,13-17 GHz区最低反射损耗−55.3 dB、有效带宽3.6 GHz;7-11 GHz区最低反射损耗−50.6 dB、有效带宽3.5 GHz。Fe3O4@TiO2与CNTs复合可协同增强磁损耗、导电损耗和界面极化。本研究为高效可调电磁吸收BF复合材料的制备提供了可行方案。

     

    Abstract: To address the longstanding challenge of achieving both broadband, strong electromagnetic absorption and lightweight, high-strength performance in conventional absorbers, basalt fibers (BF) were introduced as a structural framework, and a hierarchical core-shell Fe3O4@TiO2-CNTs architecture was employed as the absorbing component to fabricate Fe3O4@TiO2-CNTs/BF composites (FTC-O/BF). The phase structure and morphology were systematically characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and Raman spectroscopy. The electromagnetic wave absorption performance was evaluated using a vector network analyzer in combination with numerical simulations. The results demonstrate that when the Fe3O4@TiO2∶CNTs mass ratio is 5∶1 and the thickness is 5 mm, the composite exhibits a saturation magnetization of 26.8 emu·g-1, a minimum reflection loss (RLmin) of −66.8 dB, and an effective absorption bandwidth (EAB) of approximately 2.2 GHz. The FTC-O/BF composite prepared at this optimized ratio exhibits dual-band absorption characteristics at a thickness of 16 mm, with RLmin values of −55.3 dB in the 13-17 GHz range (EAB = 3.6 GHz) and −50.6 dB in the 7-11 GHz range (EAB = 3.5 GHz). The synergistic integration of Fe3O4@TiO2 and CNTs significantly enhances magnetic loss, conductive loss, and interfacial polarization. This study provides a feasible strategy for the preparation of high-performance, tunable electromagnetic-absorbing BF composites.

     

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