碳纤维与石墨烯多尺度协同增强相变储热砂浆力学和热物性试验研究

Enhancing mechanical and thermal performance of MPCM-based cement mortar through the multi-scale synergistic effect of hybrid carbon fibers and graphene nanoplatelets

  • 摘要: 微胶囊相变材料(MPCM)掺入水泥基复合材料能够赋予其潜热储能与温度调控功能,在建筑节能领域具有广阔的应用前景。然而,MPCM的引入通常会导致水泥基材料力学性能和导热性能显著下降,限制其应用,将石墨烯纳米片(GNPs)和碳纤维(CF)复掺到相变储热砂浆中,有望提升相变储热砂浆的传热效率和力学性能。本文以MPCM、GNPs和CF掺量为主要试验参数,基于力学性能、扫描电子显微镜(SEM)、孔结构、差示扫描量热(DSC)、热重测试(TGA)、导热系数以及微型房调温测试,研究了GNPs和CF掺量对MPCM基储热砂浆热物性、力学性能和热稳定性的影响。试验结果表明,MPCM掺量的增加会导致相变储热砂浆力学性能和导热系数持续降低;复掺GNPs和CF后可以在提升相变储热砂浆力学性能的同时提升其导热系数。TGA结果表明,GNPs和CF的掺入未对相变储热砂浆的热稳定性造成影响。微型房试验结果表明,GNPs和CF的加入可以提升相变储热砂浆的传热效率,保持室内温度稳定的能力。试验确定MPCM、GNPs和CF的合理掺入量分别为水泥质量的20%、0.06%和1%。

     

    Abstract: The incorporation of microencapsulated phase change materials (MPCM) into cement-based composite materials can impart latent thermal storage capacity and temperature regulation functionality, demonstrating significant potential for applications in building energy conservation. However, the incorporation of MPCM generally leads to a pronounced deterioration in the mechanical performance and thermal conductivity of cement-based materials, thereby limiting their practical application. The co-incorporation of graphene nanoplatelets (GNPs) and carbon fibers (CF) into phase change heat storage mortar is expected to enhance both the thermal transfer efficiency and mechanical properties of the composite. In this study, the contents of MPCM, GNPs, and CF were selected as the primary experimental variables. Based on mechanical performance tests, scanning electron microscopy (SEM), pore structure analysis, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), thermal conductivity measurements, and small-scale room temperature regulation tests, the effects of GNPs and CF contents on the thermophysical properties, mechanical performance, and thermal stability of MPCM-based phase change energy storage mortar were systematically investigated. The experimental results indicate that increasing the MPCM content leads to a continuous reduction in both the mechanical performance and thermal conductivity of phase change cement mortar. However, the co-incorporation of GNPs and CF enhances the mechanical performance while simultaneously improving the thermal conductivity. TGA results demonstrate that the addition of GNPs and CF has no significant effect on the thermal stability of the phase change cement mortar. The results of the small-scale room experiment indicate that the incorporation of he incorporation of GNPs and CF can enhance the heat transfer efficiency of phase change thermal energy storage mortar while maintaining indoor temperature stability. Furthermore, the optimal contents of MPCM, GNPs, and CF were determined to be 20%, 0.06%, and 1% by mass of cement, respectively.

     

/

返回文章
返回