耐候型树脂基雾封层黏结材料调控制备及性能评价

Controlled preparation and performance evaluation of weather-resistant resin-based fog seal binders

  • 摘要: 针对常规雾封层材料的渗透性能与黏结性能难以同步均衡提升以及耐候性不足的问题,定向合成了雾封层用树脂基乳化沥青,明确了其渗透性能、干燥时间与黏结性能,优化并确定了雾封层适宜材料组成及制备工艺;探明了不同老化时间下雾封层材料耐紫外老化效果,对比分析了不同改性剂对材料耐候性能的改善程度,确定了雾封层材料的适宜耐候增强剂类型及掺量,调控制备了耐候型树脂基雾封层材料;基于傅里叶变换红外光谱与荧光显微镜测试,揭示了耐候型树脂基雾封层材料改性机理及配伍性,最终实现了雾封层材料多项工作性能的均衡提升。结果表明:基于相反转工艺合成的水性环氧树脂(WER)/水性聚氨酯(WPU)改性乳化沥青的渗透深度达14.5 mm,黏结强度为0.36 MPa;1wt%炭黑掺量下耐候型树脂基雾封层材料兼具良好的紫外光吸光度与反射率,在270 h强紫外辐射(等效室外3年)后,拉伸强度性能保持率可达64%;微观测试结果表明水性树脂改性剂、炭黑均可在乳化沥青体系中有效分散与均匀分布,且具备良好相容性。本文可为耐候型树脂基雾封层的理论研究与技术推广提供有益借鉴。

     

    Abstract: Common fog seal materials face inherent challenges, particularly their insufficient weather resistance and the difficulty in synchronously balancing penetration capability with bond performance. In order to overcome these bottlenecks, a resin-based emulsified asphalt specifically for fog seals was purposefully synthesized. Its penetration capability, drying time, and bond performance were evaluated to optimize and determine the appropriate material composition and preparation process. The Ultraviolet (UV) aging resistance of the fog seal materials under varying aging durations was investigated, and the enhancement effects of different modifiers on weatherability were comparatively analyzed. Consequently, the optimal type and dosage of the weathering enhancer were identified, culminating in the controlled preparation of a weather-resistant resin-based fog seal material. Furthermore, Fourier transform infrared spectroscopy and fluorescence microscopy tests were utilized to unveil the modification mechanism and compatibility of the composite system, ultimately achieving a balanced enhancement of multiple engineering properties. The results indicated that the waterborne epoxy resin (WER)/waterborne polyurethane (WPU) modified emulsified asphalt, synthesized via the phase inversion process, achieved a penetration depth of 14.5 mm and a bond strength of 0.36 MPa. At a dosage of 1wt%, carbon black endowed the weather-resistant material with excellent UV absorbance and reflectance. After being subjected to 270 h of intense UV irradiation (equivalent to 3 years of outdoor exposure), the tensile strength retention rate of the system reached 64%. Microscopic characterizations demonstrated that both the waterborne resin modifiers and carbon black could be effectively dispersed and uniformly distributed within the emulsified asphalt matrix, exhibiting excellent compatibility. This study provides valuable insights and a theoretical foundation for advancing the research and practical implementation of weather-resistant resin-based fog seal materials.

     

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