彩色辐射制冷材料的研究进展

Research progress on colored radiative cooling materials

  • 摘要: 辐射制冷是一种被动冷却技术,通过大气窗口将热量直接辐射至外太空。传统辐射制冷材料多为白色或银白色,色彩单一,难以满足建筑围护、个人热管理等场景对美学与节能的双重要求。因此,在高制冷性能与色彩调控之间找到平衡点,成为该领域的关键问题。本文综述了彩色辐射制冷材料的基本原理、设计策略及最新进展。其光学要求在于:太阳光波段需高反射率以抑制光热吸收,大气窗口波段需高发射率以实现辐射冷却。依据着色机制,现有方案通常分两类,即光子结构型(利用结构色)与光学材料型(依赖光学材料着色)。通过比较这两类策略在呈现色彩与保持制冷性能上的异同点,并进一步介绍动态调制型材料,讨论热致变色、相变材料、湿度响应等机制的应用潜力。彩色辐射制冷材料在建筑围护、个人热管理和城市热岛缓解等方面显示出广阔的应用前景,但是,色彩多样性、环境稳定性及规模化制备仍是当前的主要障碍。

     

    Abstract: Radiative cooling is a passive cooling technology that radiates heat directly to outer space through an atmospheric window. Traditional radiant cooling materials are mostly white or silver white, and the color is single, which is difficult to meet the dual requirements of aesthetics and energy saving in scenes such as building envelope and personal thermal management. Therefore, finding a balance between high cooling performance and color control has become a key issue in this field. This paper reviews the basic principles, design strategies and latest developments of color radiative cooling materials. Its optical requirements are as follows: the solar band needs high reflectivity to suppress photothermal absorption, and the atmospheric window band needs high emissivity to achieve radiative cooling. According to the coloring mechanism, the existing schemes are generally divided into two categories: photonic structure type (using structural color) and optical material type (relying on optical material coloring). By comparing the gains and losses of these two strategies in presenting color and maintaining refrigeration performance, and further introducing dynamic modulation materials, the application potential of thermochromic, phase change materials, humidity response and other mechanisms is discussed. Color radiant cooling materials have shown good prospects in building enclosures, personal thermal management, and urban heat island mitigation. However, color diversity, environmental stability and large-scale preparation are still the main obstacles.

     

/

返回文章
返回