载荷与氯离子耦合作用下玻璃纤维增强不饱和聚酯复合材料吸湿性能
Absorption behavior of glass fiber reinforced unsaturated polyester composites subjected to chloride ion environment and sustained load
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摘要: 通过重物加载,并在氯离子环境中浸泡不同试验周期后,测试玻璃纤维增强不饱和聚酯(GFRP)复合材料的吸湿率,研究GFRP在不同应力水平下的吸湿规律。结果表明: 浸泡初期GFRP的吸湿率随时间增长较快,随后吸湿率增长逐渐变慢,当浸泡达到180 d后,吸湿率下降;GFRP的吸湿率随载荷的增加而下降,受到不同载荷大小的试件其吸湿率随时间变化规律相似;GFRP在氯离子环境中的吸湿行为呈现non-Fickian特征。基于Langmuir模型并考虑由于材料水解而发生材料"失重"的吸湿特性,提出了可描述复合材料吸湿曲线上升和下降趋势的吸湿模型,该模型可以较好地预测GFRP的吸湿量。Abstract: Loaded by weights, glass fiber reinforced unsaturated polyester (GFRP) composites were immersed in chloride ion environment at regular intervals, the moisture absorption rate of GFRP was tested to study the moisture absorption law under different stress levels.The results show that the moisture absorption rate of GFRP increases quickly with time in the initial immersion stage, then the moisture absorption rate becomes slow.Moreover, the increasing of the immersion time beyond 180 d causes a gradual decrease of the moisture absorption rate.With the increase of the load, the moisture absorption rate of GFRP decreases.And the change law of moisture absorption rate with varying time is the same for GFRP specimens under different load levels.The moisture absorption behavior of GFRP immersed in chloride ion environment has been demonstrated to show non-Fickian feature.Based on Langmuir model and taking moisture absorption feature of materials mass loss due to materials hydrolysis into accounts, a moisture absorption model was proposed to describe the increase and down trend of mositure absorption curve of composites, which can predict the moisture absorption amounts of GFRP well.