中间热处理对薄壁C/CSiC构件制备及力学性能的影响

Effect of intermediate heat treatment on the fabrication and mechanical properties of thin wall C/C SiC components

  • 摘要: 采用“化学气相渗透法+先驱体浸渍裂解法”(CVI+PIP)混合工艺制备了薄壁C/C-SiC复合材料构件,研究了C/C多孔体的热处理对C/C-SiC构件密度、变形量及力学性能的影响。研究结果表明:中间热处理可提高C/C的开孔率,有利于SiC的渗入,制备出密度较高的C/C-SiC复合材料构件;中间热处理对构件的层间剪切性能影响不大,但影响构件面内拉伸强度和整体承压性能;中间热处理会导致薄壁C/C-SiC构件在内外径和高度方向发生变形;合适的热处理温度(1600~1800℃)使C/C-SiC构件界面结合强度适中,面内拉伸强度及整体承压性能有了极大的提高;而较高的热处理温度(2100~2300℃)使碳纤维强度下降,使构件拉伸强度及整体承压性能大幅下降。

     

    Abstract: Thin wall C/C-SiC components were fabricated by "chemical vapor infiltration + precursor impregnation pyrolysis" (CVI+PIP) combined methods. The effects of intermediate heat-treated C/C porous preform on the density, deformation and mechanical properties of C/C-SiC components were investigated. The results show that the intermediate heat treatment of the C/C porous preform results in carbon with open porosity, which is favorable for SiC infiltration, leading to the preparation of a C/C-SiC component with high density. The interlaminar shear properties are not influenced observably by intermediate heat treatment, while the in-plane tensile strength and integral bearing performance are affected. The thin wall C/C-SiC components deform on the inside and outside diameter and height orientation by intermediate heat treatment. The in-plane tensile strength and integral bearing performance of the components with proper interfacial strength increase obviously after heat treatment at appropriate temperature (1600-1800℃), and the higher temperature treatment (2100-2300℃) reduces the strength of carbon fiber and reduces the tensile strength and integral bearing performance of C/C-SiC components evidently.

     

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