碳化养护对掺电石渣水泥石性能的影响

Effect of carbonation curing on the performance of cement paste added with carbide slag

  • 摘要: 为降低水泥行业的碳足迹同时回收利用电石渣,本文将电石渣作为掺合料加入碳化养护水泥中,研究了碳化养护对掺电石渣水泥石抗压强度、干燥收缩、氯离子渗透等性能的影响,并利用X射线衍射、热分析、压汞法、扫描电镜等测试手段对水泥石的微观结构进行了分析。结果表明:碳化养护提高了掺电石渣水泥石的抗压强度及抗氯离子侵蚀性能,使其电通量降低了38.17%~50.08%,56天干燥收缩率降低了8.8%~25.2%,细化了其孔结构。在保证水泥石强度不降低的前提下,约10%的电石渣可以被资源化利用,同时水泥石的固碳率可达11.19%~15.87%。利用碳化养护达到了捕捉固化二氧化碳、资源化利用电石渣、提升水泥石性能的目的。

     

    Abstract: In order to reduce the carbon footprint of cement industry and recycle carbide slag, carbide slag was added into carbonation curing cement as the mineral admixture. The influence of carbonation curing on the compressive strength, drying shrinkage, chloride ion penetration of cement paste added with carbide slag was studied, and the microstructure of cement paste was analyzed by X-ray diffraction, thermal analysis, mercury intrusion porosimetry, scanning electron microscopy, etc. The results show that carbonation curing can improve the compressive strength and chloride ion erosion resistance of cement paste added with carbide slag, reduce the electric flux by 38.17%-50.08%, reduce the 56 days drying shrinkage by 8.8%-25.2%, and refine the pore structure. About 10% of carbide slag can be used as resource under the premise that the strength of cement paste is not reduced, and the carbon fixation rate of cement paste can reach 11.19%-15.87%. The purpose of capturing and solidifying carbon dioxide, recycling carbide slag and improving the performance of cement paste are achieved by carbonation curing.

     

/

返回文章
返回