电泳沉积氧化石墨烯的碳纤维表面改性及其增强环氧树脂复合材料界面性能

Surface modification of carbon fiber(CF) deposited graphene oxide(GO) by electrophorestic deposition and interfacial properties of GO-CF/epoxy composites

  • 摘要: 采用超声辅助电泳沉积法,以异丙醇作为溶剂,在连续碳纤维(CF)表面沉积一层氧化石墨烯(GO),对CF表面进行改性。再经200℃高温处理来增强(GO)与CF之间的黏合性,从而增加CF/环氧树脂(EP)复合材料的界面结合强度。利用SEM和AFM对改性前后CF的表面形貌及微观结构变化进行了表征,通过XPS对改性前后CF表面官能团的变化进行了检测。结果表明,在CF表面沉积GO并经200℃处理后,有效地部分还原了GO(RGO),填补或桥联了CF表面缺陷,使改性后CF的拉伸强度提高了34.58%。同时,高温处理使RGO与CF之间生成牢固的化学键,从而提高了RGO与CF之间的结合强度,最终使RGO-CF/EP复合材料的界面剪切强度(IFSS)提高了69.9%。

     

    Abstract: The graphene oxide(GO) was deposited on the surface of continuous carbon fiber(CF) by ultrasonic assisted electrophoresis deposition in isopropyl alcohol for the modification of the surface of CF. Then the adhesion between GO and CF was enhanced by high temperature treatment under 200℃, which would increase the interfacial bonding strength of CF/epoxy(EP) composites. The surface morphology and microstructure of the CF before and after modification were characterized by SEM and AFM, and the changes of the surface functional groups of CF before and after modification were tested by XPS. The results show that the tensile strength of the modified CF is increased by 34.58% after deposition of GO and treatment under 200℃. The reason for the improvement is that some partially reduced GO sheets fill or bridge the defects on the surface of CF. At the same time, the adhesion between RGO and CF is enhanced by the linkage of chemical bond after high temperature treatment. And the interfacial shear strength (IFSS) of RGO-CF/EP composites is increased by 69.9%.

     

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