高导热石墨烯-碳纤维混杂增强热致形状记忆复合材料研究进展及发展趋势

马玉钦; 赵亚涛; 许威; 王杰; 陈义; 李开府

doi:10.13801/j.cnki.fhclxb.20200622.003

高导热石墨烯-碳纤维混杂增强热致形状记忆复合材料研究进展及发展趋势

doi: 10.13801/j.cnki.fhclxb.20200622.003

西安电子科技大学　机电工程学院，西安 710071

基金项目: 国家自然科学基金(51705389)；教育部产学合作协同育人项目(201902004016)；中国博士后科学基金(2017M613062)；西安电子科技大学新实验开发和新实验设备研制项目(SY1954)；西安电子科技大学研究生创新基金(5004-20109195867)；西安电子科技大学研究生创新基金(5004-20109205867)。

详细信息

通讯作者:
马玉钦，博士，讲师，硕士生导师，研究方向为先进材料成型与制造技术　 E-mail：yqma@xidian.edu.cn

中图分类号: TB381
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出版历程
- 收稿日期: 2020-05-11
- 录用日期: 2020-06-07
- 网络出版日期: 2020-06-23
- 刊出日期: 2020-10-15

Research status and development trend of high thermal conductivity graphene-carbon fiber hybrid reinforced shape memory plastic composite

School of Mechano-Electronic Engineering, Xidian University, Xi’an 710071, China

摘要

摘要: 热致形状记忆复合材料(SMPC)是一种能够对外界温度刺激做出响应的智能材料，与传统热致SMPC相比，高导热石墨烯(GR)-碳纤维(CF)混杂增强热致SMPC具有形状记忆性能优良、比强度高和导热性强等一系列优异性能，近年来受到人们广泛的关注并开展了相关研究。本文从形状记忆材料相关历史起源与应用入手，聚焦GR-CF混杂增强热致SMPC研究前沿问题，分别对该复合材料浸渗规律、成型工艺、形状记忆性能强化规律和弯曲失效规律四个方面的国内外研究现状进行了文献综述，并结合现有研究情况对其中出现的难题进行了探讨，最后指出了该热致SMPC未来有待深入研究的方向。
- 浸渗规律 /
- 智能材料 /
- 成型工艺 /
- 形状记忆 /
- 弯曲失效 /
- 石墨烯-碳纤维
Abstract: Thermally-induced shape memory plastic composite (SMPC) is an intelligent material which can respond to the external temperature stimulation. Compared with the traditional thermally-induced SMPC, the high thermal conductivity graphene(GR)-carbon fiber(CF) hybrid reinforced thermally-induced SMPC has a series of excellent properties, such as excellent shape memory performance, high specific strength and strong thermal conductivity. In recent years, people have paid much attention to it and carried out relevant research. Starting from the historical origin and applications of shape memory material, this paper focuses on the research frontier of GR-CF hybrid reinforced SMPC, and reviewes the domestic and foreign research status of the composite material in four aspects: infiltration law, molding process, shape memory performance enhancement rule and bending failure rule. Combined with the existing research situation, the future research direction of the thermally-induced SMPC is pointed out.
- infiltration law /
- intelligent material /
- molding process /
- shape memory /
- bending failure /
- graphene-carbon fiber

HTML全文

图 1 形状记忆材料(SMM)典型应用件^[7-8]

Figure 1. Typical applications of shape memory materials (SMM)^[7-8]

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图 2 碳纤维(CF)增强热致形状记忆复合材料(SMPC)与石墨烯(GR)-CF混杂增强SMPC形状固定-回复对比

Figure 2. Comparison of shape fixing-recovery between carbon fiber (CF) enhanced shape memory plastic composite (SMPC) and graphene (GR)-CF hybrid enhanced SMPC

T—Temperature of material; T_g—Glass transition temperature of material

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图 3 GR-CF混杂增强SMPC浸渗过程示意图^[11]

Figure 3. Schematic diagram of GR-CF hybrid enhanced SMPC infiltration process^[11]

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图 4 不同浸渗压力下碳纤维增强环氧树脂基复合材料弯曲强度对比^[11]

Figure 4. Comparison of bending strength of carbon fiber reinforced epoxy resin matrix composite under different infiltration pressures^[11]

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图 5 真空浸渗热压制备SMPC流程图^[28]

Figure 5. Flow chart of SMPC prepared by vacuum infiltration hot pressing process^[28]

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图 6 真空浸渗热压SMPC试验系统结构^[28]

Figure 6. Structure of SMPC test system by vacuum infiltration hot pressing^[28]

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图 7 65vol% CF增强环氧树脂基复合材料微观组织图^[28]

Figure 7. Microstructure diagrams of 65vol% CF reinforced epoxy resin matrix composite^[28]

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图 8 50vol% CF-50vol%玄武岩纤维(BF)混杂增强环氧树脂基复合材料三点弯曲有限元模型

Figure 8. Three-point bending finite element model of 50vol% CF-50vol% basalt fiber (BF) hybrid reinforced epoxy resin composite

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图 9 CF-BF混杂增强环氧树脂基复合材料三点弯曲有限元仿真与试验结果趋势对比

Figure 9. Trend comparison of three point bending finite element simulation and test results for CF-BF hybrid reinforced epoxy resin matrix composites

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图 10 不同模压温度下CF增强环氧树脂基SMPC形状固定率和回复率^[36]

Figure 10. CF reinforced epoxy resin matrix SMPC shape fixation rate and recovery rate at different molding temperatures^[36]

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图 11 模压温度70℃时65vol% CF增强环氧树脂基SMPC微观组织图^[36]

Figure 11. Microstructure diagrams of 65vol% CF reinforced epoxy resin matrix SMPC at mold pressing temperature of 70℃^[36]

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