留言板

尊敬的读者、作者、审稿人, 关于本刊的投稿、审稿、编辑和出版的任何问题, 您可以本页添加留言。我们将尽快给您答复。谢谢您的支持!

姓名
邮箱
手机号码
标题
留言内容
验证码

聚吡咯/碳纤维纸电热复合材料的制备及性能

汤龙其 令旭霞 王士华 郭帅 龙柱

汤龙其, 令旭霞, 王士华, 等. 聚吡咯/碳纤维纸电热复合材料的制备及性能[J]. 复合材料学报, 2020, 37(6): 1426-1433. doi: 10.13801/j.cnki.fhclxb.20191021.002
引用本文: 汤龙其, 令旭霞, 王士华, 等. 聚吡咯/碳纤维纸电热复合材料的制备及性能[J]. 复合材料学报, 2020, 37(6): 1426-1433. doi: 10.13801/j.cnki.fhclxb.20191021.002
TANG Longqi, LING Xuxia, WANG Shihua, et al. Preparation and properties of polypyrrole/carbon fiber paper electrothermal composites[J]. Acta Materiae Compositae Sinica, 2020, 37(6): 1426-1433. doi: 10.13801/j.cnki.fhclxb.20191021.002
Citation: TANG Longqi, LING Xuxia, WANG Shihua, et al. Preparation and properties of polypyrrole/carbon fiber paper electrothermal composites[J]. Acta Materiae Compositae Sinica, 2020, 37(6): 1426-1433. doi: 10.13801/j.cnki.fhclxb.20191021.002

聚吡咯/碳纤维纸电热复合材料的制备及性能

doi: 10.13801/j.cnki.fhclxb.20191021.002
详细信息
    通讯作者:

    龙柱,博士,教授,博士生导师,研究方向为高性能纤维纸基材料、特种纸与功能纸、生物基化学品和材料 E-mail:longzhu@jiangnan.edu.cn

  • 中图分类号: TB332;TS762

Preparation and properties of polypyrrole/carbon fiber paper electrothermal composites

  • 摘要: 在碳纤维纸(CPP)上采用气相聚合法使吡咯单体发生聚合生成聚吡咯(PPY),制备聚吡咯/碳纤维(PPY/CF)纸导电发热复合材料。通过FTIR、SEM、XRD对PPY/CF纸复合材料进行测试分析,并探究了CPP中CF的最佳质量分数及FeCl3的最优溶度,研究了PPY/CF纸复合材料的力学性能和电热性能。结果表明,成功制备了PPY/CF纸复合材料,且PPY主要附着在芳纶浆粕上;采用CF质量分数为10 wt%的CPP且FeCl3浓度为1.2 mol/L时,制备的PPY/CF纸复合材料具有最低的电阻率,为0.139 Ω·cm;PPY/CF纸复合材料与CPP相比不仅力学性能大幅提高,而且在低电压下,PPY/CF纸复合材料具有导电性能稳定、发热效果显著、热稳定性好等优点。

     

  • 图  1  聚吡咯/碳纤维(PPY/CF)纸复合材料(a)和碳纤维纸(CPP)(b)的FTIR图谱

    Figure  1.  FTIR spectra of polypyrrole carbon fiber(PPY/CF) paper composites (a) and carbon fiber paper (CPP) (b)

    图  2  CPP((a),(d))和PPY/CF纸复合材料((b),(c),(e))的SEM图像

    Figure  2.  SEM images of CPP((a),(d)) and PPY/CF paper composites((b),(c),(e))

    图  3  CPP和PPY/CF纸复合材料的XRD图谱

    Figure  3.  XRD patterns of CPP and PPY/CF paper composites

    图  4  CF质量分数对CPP电阻率和抗张指数的影响

    Figure  4.  Effect of CF mass fraction on resistivity and tensile index of CPP

    图  5  FeCl3浓度对PPY/CF纸复合材料电阻率的影响

    Figure  5.  Effect of FeCl3 concentration on electrical resistivity of PPY/CF paper composites

    图  6  PPY/CF纸复合材料的热成像图(a)和拍摄原图(b)及CPP的热成像图(c)和拍摄原图(d)

    Figure  6.  Thermal imaging(a) and picture(b) of PPY/CF paper composites and thermal imaging(c) and picture(d) of CPP

    图  7  PPY/CF纸复合材料((a)、(b))和CPP ((c)、(d))的小灯泡实验

    Figure  7.  Small bulb experiment of PPY/CF paper composite ((a), (b)) and CPP ((c), (d))

    图  8  不同pH值下PPY/CF纸基复合材料的电阻率

    Figure  8.  Resistivity of PPY/CF paper composites at different pH values

    图  9  不同空气湿度下PPY/CF纸复合材料的电阻率

    Figure  9.  Resistivity of PPY/CF paper composites under different air humidity

    图  10  PPY/CF纸复合材料多次使用下的电阻率

    Figure  10.  Resistivity of PPY/CF paper composite used multiple times

    图  11  PPY/CF纸复合材料的TG曲线

    Figure  11.  TG curves of PPY/CF paper composite

    表  1  CPP和PPY/CF纸复合材料的力学性能

    Table  1.   Mechanical properties of CPP and PPY/CF paper composites

    CPPPPY/CF paper composite
    Tensile index/(N·m·g−1)10.891±0.12221.110±0.150
    Burst resistance index/(kPa·m2·g−1)2.123±0.1134.569±0.185
    Tear index/(mN·m2·g−1)3.502±0.1506.563±0.115
    下载: 导出CSV
  • [1] BEGUM Y K, LALE I S, SELMIYE A G. Flexible carbon-cellulose fiber-based composite gas diffusion layer for polymer electrolyte membrane fuel cells[J]. Journal of Materials Science,2017,52(9):4968-4976. doi: 10.1007/s10853-016-0734-6
    [2] QIAN R R, CHEN C S. Effect of conductive carbon material content and structure in carbon fiber paper made from carbon felt on the performance of a proton exchange membrane fuel cell[J]. Renewable Energy,2015,78:364-373. doi: 10.1016/j.renene.2015.01.021
    [3] 施云舟, 王彪. 碳纤维导电纸的研究现状及其应用[J]. 化工新型材, 2014(4):192-194.

    SHI Yunzhou, WANG Biao. Research status and application of carbon fiber conductive paper[J]. New Chemical Materials,2014(4):192-194(in Chinese).
    [4] 王茂章, 贺福. 碳纤维的制造、性质及其应用[M]. 北京: 科学出版社, 1984: 23-27.

    WANG Maozhang. HE Fu. The manufacture, properties and application of carbon fiber[M]. Beijing: Science Press, 1984: 23-27(in Chinese).
    [5] 张美云, 钟林新, 彭新文. 碳纤维屏蔽纸制造过程中纤维分散性能的研究[J]. 中华纸业, 2008, 29(6):10-13. doi: 10.3969/j.issn.1007-9211.2008.06.002

    ZHANG Meiyun, ZHONG Linxin, PENG Xinwen. Study on fiber dispersion properties in carbon fiber shielding paper manufacturing process[J]. Zhonghua Paper,2008,29(6):10-13(in Chinese). doi: 10.3969/j.issn.1007-9211.2008.06.002
    [6] 张旺玺. 聚丙烯腈基碳纤维[M]. 上海: 东华大学出版社, 2005: 12-19.

    ZHANG Wangxi. Polyacrylonitrile-based carbon fiber[M]. Shanghai: Donghua University Press, 2005: 12-19(in Chinese).
    [7] 张美云, 钟林新, 陈均志, 等. 碳纤维导电纸的性能及应用[J]. 中国造纸, 2008, 27(3):13-17. doi: 10.3969/j.issn.0254-508X.2008.03.004

    ZHANG Meiyun, ZHONG Linxin, CHEN Junzhi, et al. Performance and application of carbon fiber conductive paper[J]. China Paper,2008,27(3):13-17(in Chinese). doi: 10.3969/j.issn.0254-508X.2008.03.004
    [8] KAYNAK A, BELTRAN R. Effect of synthesis parameters on the electrical conductivity of polypyrrole-coated poly(ethylene terephthalate) fabrics[J]. Polymer International,2003,52(6):1021-1026. doi: 10.1002/pi.1195
    [9] 李希萌, 厉英, 胡传波. 聚吡咯纳米复合材料制备及应用研究进展[J]. 化工进展, 2018, 37(4):1489-1500.

    LI Ximeng, LI Ying, HU Chuanbo. Progress in preparation and application of polypyrrole nanocomposites[J]. Chemical Industry and Engineering Progress,2018,37(4):1489-1500(in Chinese).
    [10] OMASTOVÁ M, PAVLINEC J, PIOINTECK J, et al. Synthesis electrical properties and stability of polypyrrole-containing conducting polymer composites[J]. Polymer International,1997,43(2):109-116. doi: 10.1002/(SICI)1097-0126(199706)43:2<109::AID-PI707>3.0.CO;2-T
    [11] LEE J Y, PARK D W, LIM J O. Polypyrrole-coated woven fabric as a flexible surface-heating element[J]. Macromolecular Research,2003,11(6):481-487. doi: 10.1007/BF03218980
    [12] SHANG S, YANG X, TAO X M, et al. Vapor-phase polymerization of pyrrole on flexible substrate at low temperature and its application in heat generation[J]. Polymer International,2010,59(2):204-211.
    [13] 黄文靖, 丁子先, 邱学青, 等. 自组装聚合法制备木质素磺酸/聚吡咯柔性导电纸[J]. 高等学校化学学报, 2018, 39(11):255-264.

    HUANG Wenjing, DING Zixian, QIU Xueqing, et al. Preparation of lignosulfonic acid/polypyrrole flexible conductive paper by self-assembled polymerization[J]. Chemical Journal of Chinese Universities,2018,39(11):255-264(in Chinese).
    [14] 丁春跃. 原位聚合法制备聚吡咯包覆型导电纸的工艺与机理研究[D]. 哈尔滨: 东北林业大学, 2010.

    DING Chunyue. Study on the preparation and mechanism of polypyrrole coated conductive paper by in-situ polymerization[D]. Harbin: Northeast Forestry University, 2010(in Chinese).
    [15] 陈京环, 钱学仁, 李翠翠, 等. 气相聚合法制备聚吡咯导电纸[J]. 中国造纸, 2008, 27(4):5-8. doi: 10.3969/j.issn.0254-508X.2008.04.002

    CHEN Jinghuan, QIAN Xueren, LI Cuicui, et al. Preparation of polypyrrole conductive paper by gas phase polymerization[J]. China Paper,2008,27(4):5-8(in Chinese). doi: 10.3969/j.issn.0254-508X.2008.04.002
    [16] 薛茹君. 电磁屏蔽材料及导电填料的研究进展[J]. 涂料技术与文摘, 2004, 25(3):3-7. doi: 10.3969/j.issn.1672-2418.2004.03.002

    XUE Rujun. Research progress in electromagnetic shielding materials and conductive fillers[J]. Coating Technology and Abstracts,2004,25(3):3-7(in Chinese). doi: 10.3969/j.issn.1672-2418.2004.03.002
    [17] 颜杰, 唐楷. 炭黑复合导电材料的导电机理[J]. 化工新型材料, 2005, 33(12):76-78. doi: 10.3969/j.issn.1006-3536.2005.12.024

    YAN Jie, TANG Kai. Conductive mechanism of carbon black composite conductive materials[J]. Chemical Engineering Materials,2005,33(12):76-78(in Chinese). doi: 10.3969/j.issn.1006-3536.2005.12.024
    [18] 于万永, 赵磊, 王宁, 等. 聚乙烯醇-聚吡咯复合纳米纤维的制备及其导电性能[J]. 复合材料学报, 2018, 35(5):1059-1065.

    YU Wanyong, ZHAO Lei, WANG Ning, et al. Fabrication and conductive properties of polyvinyl alcohol-polypyrrole composite nano fibers[J]. Acta Materiae Compositae Sinica,2018,35(5):1059-1065(in Chinese).
    [19] 付长璟, 李爽, 宋春来, 等. 聚吡咯/氧化石墨复合材料的制备及其电容性能[J]. 复合材料学报, 2016, 33(3):572-579.

    FU Changjing, LI Shuang, SONG Chunlai, et al. Preparation of polypyrrole/graphite oxide composite and its capacitance performance[J]. Acta Materiae Compositae Sinica,2016,33(3):572-579(in Chinese).
    [20] 林生岭, 曹旭, 林琪, 等. 化学氧化法合成聚吡咯工艺条件优化及电化学性能[J]. 江苏科技大学学报(自然科学版), 2010, 24(4):353-356.

    LIN Shengling, CAO Xu, LIN Qi, et al. Optimization of process conditions and electrochemical properties of polypyrrole by chemical oxidation[J]. Journal of Jiangsu University of Science and Technology (Natural Science Edition),2010,24(4):353-356(in Chinese).
    [21] MATHYS G I, TRUONG V T. Spectroscopic study of thermo-oxidative degradation of polypyrrole powder by FT-IR[J]. Synthetic Metals,1997,89(2):103-109. doi: 10.1016/S0379-6779(98)80122-7
    [22] VARESANO A, DALLACQUA L, TONIN C. A study on the electrical conductivity decay of polypyrrole coated wooltextiles[J]. Polymer Degradation & Stability,2005,89(1):125-132.
    [23] FORINTOS N, CZIGÁNY T. Multifunctional application of carbon fiber reinforced polymer composites: Electrical properties of the reinforcing carbon fibers: A short review[J]. Composites Part B: Engineering,2019,162:331-343. doi: 10.1016/j.compositesb.2018.10.098
  • 加载中
图(11) / 表(1)
计量
  • 文章访问数:  1004
  • HTML全文浏览量:  200
  • PDF下载量:  75
  • 被引次数: 0
出版历程
  • 收稿日期:  2019-07-02
  • 录用日期:  2019-09-20
  • 网络出版日期:  2019-10-21
  • 刊出日期:  2020-06-15

目录

    /

    返回文章
    返回