Orthogonal experiment on mechanical properties of basalt fiber-carbon fiber/slag concrete
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摘要: 应用正交试验法开展了16组玄武岩-碳纤维(BF-CF)/矿渣混凝土和1组C40级基准混凝土的塌落度、立方体抗压强度和劈裂抗拉强度试验,研究了BF、CF和矿渣三种因素对BF-CF/矿渣混凝土力学性能的影响。结果表明:BF-CF/矿渣混凝土立方体抗压强度和劈裂抗拉强度均高于C40基准混凝土,立方体抗压强度最大提高了21.0%,劈裂抗拉强度最大提高了35.3%。BF和CF的掺入均会减小混凝土的塌落度,BF对于塌落度的减小更加明显,BF对塌落度的最大降幅为67.1%;矿渣代砂率是影响BF-CF/矿渣混凝土立方体抗压强度的显著因素,随着矿渣代砂率的增大,立方体抗压强度先增大后减小,矿渣对立方体抗压强度的最大提高幅度为7.6%;BF是影响BF-CF/矿渣混凝土劈裂抗拉强度的显著因素,劈裂抗拉强度随BF体积率的增加而增大,BF对劈裂抗拉强度的最大增幅为12.0%,CF对劈裂抗拉强度的提升不明显。对正交试验的结果进行回归分析得出BF-CF/矿渣混凝土立方体抗压强度和劈裂抗拉强度预测模型,模型精度较高。Abstract: The slump, cube compressive strength and splitting tensile strength tests of 16 groups of basalt fiber-carbon fiber(BF-CF)/slag concrete and 1 group of C40 reference concrete were conducted by orthogonal experimental method. The effects of BF, CF and slag on the mechanical properties of BF-CF/slag concrete were investigated. The test results show that the cube compressive strength and splitting tensile strength of BF-CF/slag concrete are higher than the cube compressive strength and splitting tensile strength of C40 reference concrete, i.e., the maximum increase of cube compressive strength is 21.0%, and the maximum increase of splitting tensile strength is 35.3%. The addition of BF and CF can reduce the slump of concrete, and BF can reduce the slump more significantly. The maximum drop of BF to the slump is 67.1%. The mass fraction of slag replacing for sand is a significant factor affecting the cube compressive strength of BF-CF/slag concrete. With the increase of mass fraction of slag replacing for sand, the cube compressive strength first increases and then decreases, and the maximum increase of slag to the cube compressive strength is 7.6%. BF is a significant factor affecting the tensile strength of BF-CF/slag concrete, and the tensile strength increases with the increase of the volume fraction of BF. The maximum increase of BF to the tensile strength is 12.0%, and the increase of CF to the tensile strength is not obvious. The results of the orthogonal experiment were regressed, and the prediction models of the cube compressive strength and splitting tensile strength of the BF-CF/slag concrete were obtained, and the accuracy of model is high.
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图 4 BF体积分数(Vb)、CF体积分数(Vc)和矿渣代砂率(Rs)对BF-CF/矿渣混凝土塌落度、立方体抗压强度、劈裂抗拉强度和拉压比的影响
Figure 4. Effects of volume fraction of BF(Vb), volume fraction of CF(Vc) and mass ratio of slag replacing for sand(Rs) on slump, cube compressive strength, splitting tensile strength and tension-compression ratio of BF-CF/slag concrete
表 1 BF和CF主要性能参数
Table 1. Main performance parameters of BF and CF
Fiber BF CF Density/(g·cm–3) 2.8 1.76 Tensile strength/MPa 4 000 3 800 Modulus of elasticity/GPa 100 230 Monofilament diameter/μm 12 8 Length/mm 12 6 Elongation at break/% 3.1 1.5 表 2 矿渣的主要成分及性能
Table 2. Chemical composition and property of copper slag
wt% Fe2O3 SiO2 Al2O3 CaO Cu2O P2O5 Burning loss 41.5 29 4.2 7 0.5 − 3 表 3 矿渣和天然石英砂的性能指标
Table 3. Performance indexes of copper slag and natural fine aggregate
Test item Fineness modulus Apparent density/(kg·m–3) Bulk density/(kg·m–3) Copper slag 3.3 2 650 1 900 Natural fine aggregate 1.4 3 600 1 750 表 4 细骨料细度模数
Table 4. Fineness modulus of fine aggregate
Rs/wt% 0 20 40 60 80 Fineness modulus 1.40 2.17 2.36 2.62 2.94 Note: Rs—Mass fraction of slag replacing for sand. 表 5 BF-CF/矿渣混凝土正交试验因素和水平
Table 5. Factors and levels of orthogonal test of BF-CF/slag concrete
Level Factor Vb(A)/vol% Vc(B)/vol% Rs(C)/wt% Blank column(D) Blank column(E) 1 0.1 0.1 20 1 1 2 0.2 0.2 40 2 2 3 0.3 0.3 60 3 3 4 0.4 0.4 80 4 4 Notes:Vb—volume fraction of BF in concrete, Vc—Volume fraction of CF in concrete. 表 6 C40基准混凝土配合比
Table 6. Proportion of C40 reference concrete
kg·m−3 Type Cement Fly ash Sand Stone Water Water reducer S-1 405 71 613 1 242 162 5.24 Notes:S—Reference concrete. 表 7 C40基准混凝土和BF-CF/矿渣混凝土塌落度和强度试验结果
Table 7. Test results of slump and strength of C40 reference concrete and BF-CF/slag concrete
Material type Factor Concrete slump/mm Cube compressive
strength fcu/MPaSplitting tensile
strength fts/MPaTension-compression
ratio (fts/fcu)A/
vol%B/
vol%C/
wt%S-1 0 0 0 178 44.3 3.31 0.074718 ZJ-1 0.1 0.1 20 168 47.2 3.70 0.078390 ZJ-2 0.1 0.2 40 143 48.7 3.79 0.077823 ZJ-3 0.1 0.3 60 125 53.6 4.18 0.077985 ZJ-4 0.1 0.4 80 81 47.8 4.17 0.087238 ZJ-5 0.2 0.1 40 138 48.1 4.11 0.085447 ZJ-6 0.2 0.2 20 120 47.9 3.99 0.083299 ZJ-7 0.2 0.3 80 78 48.0 4.24 0.088333 ZJ-8 0.2 0.4 60 93 50.4 4.30 0.085317 ZJ-9 0.3 0.1 60 107 51.8 4.40 0.084942 ZJ-10 0.3 0.2 20 91 47.3 4.26 0.090063 ZJ-11 0.3 0.3 80 76 50.1 4.24 0.084631 ZJ-12 0.3 0.4 40 65 52.2 4.38 0.083908 ZJ-13 0.4 0.1 80 73 45.5 4.41 0.096923 ZJ-14 0.4 0.2 60 41 50.4 4.45 0.088294 ZJ-15 0.4 0.3 40 33 51.0 4.48 0.087843 ZJ-16 0.4 0.4 20 23 49.8 4.33 0.086948 Notes: S—Reference concrete; ZJ—BF-CF/slag concrete. 表 8 BF-CF/矿渣混凝土塌落度和强度的极差分析结果
Table 8. Range analysis results of slump and strength of BF-CF/slag concrete
Examination index Range calculation BF CF Slag Blank column(D) Blank column (E) Concrete slump/mm Bi1 129.25 121.5 100.5 88.00 96.25 Bi2 107.25 98.75 94.75 85.25 95.75 Bi3 84.75 78.00 91.5 96.25 84.00 Bi4 42.50 65.50 77.00 94.25 87.75 Ri 86.75 56.00 23.50 11.00 12.25 Cube compressive strength fcu/MPa Bi1 48.8 48.2 48.6 49.6 49.0 Bi2 49.0 48.8 49.5 49.6 49.8 Bi3 50.5 51.0 52.3 48.7 49.1 Bi4 49.4 50.4 47.0 49.7 49.6 Ri 1.7 2.8 5.3 1.0 0.8 Splitting tensile strength fts/MPa Bi1 3.96 4.16 4.07 4.19 4.19 Bi2 4.16 4.12 4.19 4.26 4.24 Bi3 4.32 4.29 4.33 4.19 4.24 Bi4 4.42 4.30 4.27 4.22 4.19 Ri 0.46 0.18 0.27 0.07 0.05 Tension-compression ratio (fts/fcu) Bi1 0.080359 0.086425 0.088317 0.084731 0.085403 Bi2 0.085990 0.084870 0.083755 0.085831 0.085529 Bi3 0.085886 0.084698 0.084135 0.086174 0.086402 Bi4 0.090002 0.085853 0.090640 0.085111 0.084512 Ri 0.009643 0.001727 0.006885 0.001442 0.001891 Notes: Bij—Average of the test results of factor i at level j; Ri—Range value of factor i. 表 9 BF-CF/矿渣混凝土塌落度和强度的方差分析检验
Table 9. Variance analysis of slump and strength of BF-CF/slag concrete
Examination index Source of variation SS DF MS F Significance Concrete slump/mm BF 16 473.688 3 5 491.229 40.576 ** CF 6 593.062 3 2 197.687 16.239 * Slag 557.062 3 185.687 1.372 − Error 759.375 6 126.563 Cube compressive strength fcu/MPa BF 6.372 3 2.124 2.848 − CF 17.142 3 5.714 7.661 * Slag 41.848 3 13.949 18.703 ** Error 4.475 6 0.746 Splitting tensile
strength fts/MPaBF 0.480 3 0.160 37.765 ** CF 0.094 3 0.031 7.376 * Slag 0.160 3 0.053 12.566 * Error 0.025 6 0.004 Tension-compression ratio (fts/fcu) BF 0 3 0.0000624710 30.272 ** CF 0.0000080623 3 0.0000026873 1.302 − Slag 0 3 0.0000481120 23.313 * Error 0.0000123852 6 0.0000020643 Notes: SS—Sum of squares; DF—Degree of freedom; MS—Mean square; F—F-value; **—Highly marked; *—Marked; −—No marked; F0.05(3,6)=4.76. Literature Numbers Vb/
vol%Vc/
vol%Rs/
wt%Cube compressive strength /MPa Splitting tensile strength /MPa Actual measurement Prediction Relative error/% Actual measurement Prediction Relative error/% Literature[27](C40) 1 0.1 — — 46.20 41.73 −9.68 3.30 3.28 −0.51 2 0.15 — — 44.70 41.80 −6.50 3.74 3.36 −10.16 3 0.2 — — 43.70 41.86 −4.21 4.01 3.44 −14.30 Literature[28](C30) 4 0.05 — — 39.50 40.57 2.70 3.75 3.72 −0.89 5 0.1 — — 37.80 40.63 7.49 3.86 3.79 −1.73 6 0.2 — — 35.10 40.76 16.13 4.00 3.95 −1.34 Literature[29](C30) 7 0.1 — — 43.20 39.23 −9.19 3.76 3.62 −3.64 Literature[29](C40) 8 0.1 — — 54.80 49.83 −9.07 4.43 4.15 −6.25 9 0.2 — — 51.60 49.96 −3.18 3.69 4.31 −8.18 Literature[30](C40) 10 — — 30 48.80 52.31 7.20 3.73 4.00 7.34 11 — — 50 43.80 51.99 18.69 3.59 4.08 13.64 12 — 0.1 — 57.41 53.58 −6.67 4.15 3.95 −4.86 13 — 0.2 — 60.26 54.36 −9.79 4.66 4.01 −14.02 14 — 0.3 — 68.44 55.14 −19.43 5.01 4.06 −18.87 15 — 0.1 30 51.76 53.58 −3.52 3.95 4.06 2.83 16 — 0.2 30 54.30 54.36 0.11 4.46 4.12 −7.65 17 — 0.3 30 61.43 55.14 −10.24 4.93 4.18 −15.21 Literature[31](C30, mw/mc=0.55) 18 — — 20 38.60 34.28 −11.20 2.80 2.78 −0.86 19 — — 40 33.20 33.95 2.26 2.70 2.85 5.61 20 — — 60 34.00 33.63 −1.10 2.80 2.93 4.55 21 — — 80 32.80 33.30 1.52 2.65 3.00 13.33 22 — — 100 30.70 32.98 7.41 — — — Literature[31](C40, mw/ mc=0.45) 23 — — 20 50.20 45.48 −9.41 2.55 2.48 −2.91 24 — — 40 48.20 45.15 −6.33 2.35 2.55 8.58 25 — — 60 50.20 44.83 −10.71 2.40 2.63 9.47 26 — — 80 46.70 44.50 −4.71 2.30 2.70 17.53 27 — — 100 47.80 44.18 −7.58 — — — Note: mw/mc—Water-cementc mass ratio. -
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