One-step synthesis of polyaniline nanowire/self-supported graphene composite with excellent cycling stability

XIN Guoxiang; WANG Mengmeng; ZHAI Yao; WANG Yanhui; ZHANG Bangwen; SONG Jinling; LIU Xiaoxu

doi:10.13801/j.cnki.fhclxb.20200730.001

Volume 38 Issue 4

Apr. 2021

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Article Navigation > Acta Materiae Compositae Sinica > 2021 > 38(4): 1272-1282

XIN Guoxiang, WANG Mengmeng, ZHAI Yao, et al. One-step synthesis of polyaniline nanowire/self-supported graphene composite with excellent cycling stability[J]. Acta Materiae Compositae Sinica, 2021, 38(4): 1272-1282. doi: 10.13801/j.cnki.fhclxb.20200730.001

Citation:

XIN Guoxiang, WANG Mengmeng, ZHAI Yao, et al. One-step synthesis of polyaniline nanowire/self-supported graphene composite with excellent cycling stability[J]. Acta Materiae Compositae Sinica, 2021, 38(4): 1272-1282. doi: 10.13801/j.cnki.fhclxb.20200730.001

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One-step synthesis of polyaniline nanowire/self-supported graphene composite with excellent cycling stability

doi: 10.13801/j.cnki.fhclxb.20200730.001

1.
School of Materials and Metallurgy, Inner Mongolia of Science and Technology, Baotou 014010, China
2.
College of Materials Science and Engineering, Yanshan University, Qinhuangdao 066004, China
3.
Faculty of Physics, Hebei Normal University of Science and Technology, Qinhuangdao 066004, China

Received Date: 2020-06-01
Accepted Date: 2020-07-22

Available Online: 2020-07-31

Publish Date: 2021-04-08

Abstract

Abstract

The polyaniline nanowire/self-supported graphene (PANI/SGr) composite was synthesized by one-step electrochemical exfoliation and electrodeposition method using graphite paper. The directional migration of electrolyte ions and the electropolymerization of aniline monomers through the electrical field simultaneously occurred in the mixed solution including Na₂SO₄, HCl and aniline (An) monomers. The stability of the PANI/SGr composite is enhanced by the combination of the new-born SGr with high activity and PANI. The uniform distribution of the nanowire-like PANI is achieved on the surface of the SGr. The PANI nanowires lead to the formation of the three-dimensional network architecture, where the existence of pores facilitates the diffusion of electrolyte ions into the internal structure of the PANI/SGr composite. The electrochemical tests of the PANI/SGr composite were conducted as a supercapacitor electrode material. The specific capacitance of 453 F·g⁻¹ at a scan rate of 2 mV·s⁻¹ is achieved. The rate capability of the PANI/SGr composite at the current densities of 0.5-10 A·g⁻¹ is up to 73.1%. The cycling stability of the PANI/SGr composite is as high as 87.3% after 10000 discharge-charge cycles at the current density of 1 A·g⁻¹. All of these results indicate that the PANI/SGr composite possesses good capacitive performance and excellent cycling stability. The PANI/SGr composite is promising for supercapacitor electrode materials.
- one-step method,
- polyaniline,
- self-supported graphene,
- supercapacitors,
- cycling stability
Long Abstrsct
Innovation Points

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References(38)

References

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