[Ni(CH
3COO)
2+PVP]-[Zn(CH
3COO)
2+PVP]-[Ti(OC
4H
9)
4+CH
3COOH+PVP] composite cables had been fabricated through modified electrospinning equipment. NiO-ZnTiO
3-TiO
2 coaxial trilayered nanocables were obtained by the calcination of the relevant composite cables at 600℃. The samples were characterized by use of thermogravimetric-differential thermal analysis (TG-DTA), X-ray diffractometry (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). Formation mechanism of NiO-ZnTiO
3-TiO
2 coaxial trilayered nanocables was preliminarily proposed. The results show that the samples are NiO-ZnTiO
3-TiO
2 coaxial trilayered nanocables. The core layer is NiO, and its diameter is about (42.024±4.405) nm. The middle layer is ZnTiO
3, and its thickness is about (55.385±7.681) nm. The outer layer is TiO
2, the thickness is about (70.747±7.373) nm.