Design of BiMn-doped Pd modified GO/MOF-74-Co composites for electrocatalytic oxidation of ethylene glycol

MO Han; WAN Zhengrui; ZHONG Yuting; WU Zhirui; HU Yalan; LIU Hongying; ZHOU Liqun

doi:10.13801/j.cnki.fhclxb.20210330.004

Volume 39 Issue 1

Jan. 2022

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MO Han, WAN Zhengrui, ZHONG Yuting, et al. Design of BiMn-doped Pd modified GO/MOF-74-Co composites for electrocatalytic oxidation of ethylene glycol[J]. Acta Materiae Compositae Sinica, 2022, 39(1): 203-212. doi: 10.13801/j.cnki.fhclxb.20210330.004

Citation:

MO Han, WAN Zhengrui, ZHONG Yuting, et al. Design of BiMn-doped Pd modified GO/MOF-74-Co composites for electrocatalytic oxidation of ethylene glycol[J]. Acta Materiae Compositae Sinica, 2022, 39(1): 203-212. doi: 10.13801/j.cnki.fhclxb.20210330.004

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Design of BiMn-doped Pd modified GO/MOF-74-Co composites for electrocatalytic oxidation of ethylene glycol

doi: 10.13801/j.cnki.fhclxb.20210330.004

College of Chemistry and Chemical Engineering, Collaborative Innovation Center for Advanced Organic Chemical Materials Co-constructed by the Province and Ministry, Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, Hubei University, Wuhan 430062, China

Received Date: 2021-01-15
Accepted Date: 2021-03-25
Rev Recd Date: 2021-03-19

Available Online: 2021-03-31

Publish Date: 2022-01-15

Abstract

Abstract

BiMn co-doped Pd alloy nanoparticles were successfully modified on the 3D pyramidal columnar-like reduced graphene oxide (rGO)/metal-organic frameworks (MOFs)-74-Co to obtain a new composite electrocatalyst PdBiMn@rGO/MOF-74-Co in which the mean particle diameter of Pd-Bi-Mn particles was about 7.8 nm, and MOF-74-Co was a porous face-centered hexagonal unit cell. PdBiMn@rGO/MOF-74-Co catalyst exhibites the highest catalytic activity and durability towards ethylene glycol (EG) electrooxidation under alkaline condition. The excellent electrocatalytic performance is mainly attributed to the strong synergistic effects of Pd, Bi and Mn nanoalloys and abundant reaction active sites in the catalyst, which are beneficial to adsorb more oxygen-containing substances and significantly enhance the resistance to toxicity and stability of the ternary catalyst. Furthermore, the unique microstructure of rGO/MOF-74-Co can provide superior electron transfer properties and multi-porous for the PdBiMn@rGO/MOF-74-Co electrocatalyst. Besides, the mechanism of electrocatalytic oxidation of EG drew up a detailed analysis. The novel composites’ design and outstanding performance would provide an essential reference for the application and development of direct alcohol fuel cells (DAFCs).
- Pd-Bi-Mn nanoalloys,
- graphene oxide,
- MOF-74-Co,
- electrocatalytic oxidation,
- ethylene glycol
Long Abstrsct
Innovation Points

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References(26)

References

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