Preparation of ammoniated tobacco leave powder residue biochar and its adsorption behavior on Cr(VI)

YANG Jinhui; HU Shiqin; YANG Bin; XIE Shuibo; LEI Zengjiang; LI Cong

doi:10.13801/j.cnki.fhclxb.20210320.001

Volume 39 Issue 1

Jan. 2022

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YANG Jinhui, HU Shiqin, YANG Bin, et al. Preparation of ammoniated tobacco leave powder residue biochar and its adsorption behavior on Cr(VI)[J]. Acta Materiae Compositae Sinica, 2022, 39(1): 222-231. doi: 10.13801/j.cnki.fhclxb.20210320.001

Citation:

YANG Jinhui, HU Shiqin, YANG Bin, et al. Preparation of ammoniated tobacco leave powder residue biochar and its adsorption behavior on Cr(VI)[J]. Acta Materiae Compositae Sinica, 2022, 39(1): 222-231. doi: 10.13801/j.cnki.fhclxb.20210320.001

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Preparation of ammoniated tobacco leave powder residue biochar and its adsorption behavior on Cr(VI)

doi: 10.13801/j.cnki.fhclxb.20210320.001

University of South China, School of Civil Engineering, Hunan 421001, China

Received Date: 2021-01-14
Accepted Date: 2021-03-15
Rev Recd Date: 2021-03-04

Available Online: 2021-03-22

Publish Date: 2022-01-15

Abstract

Abstract

Using the waste cigarette leave powder residue as raw materials, after carbonization, the amino functional group was introduced to prepare the ammoniated tobacco leave powder residue biochar (NH ₂/TPB), and the effects of pH, dosage, temperature and adsorption time on NH ₂/TPB adsorption of Cr(Ⅵ) were studied. The mechanism was analyzed by scanning electron microscopy (SEM), Fourier infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS) and other techniques. The results show that when the initial concentration is 210 mg/L, pH=4, dosage is 0.8 g/L, temperature is 45℃, and adsorption time is 120 min, the maximum adsorption capacity of NH ₂/TPB for Cr(Ⅵ) is 103.627 mg/g. The adsorption process conforms the quasi-second-order kinetic model and Langmuir adsorption isotherm model. The adsorption and removal mechanism of Cr(Ⅵ) mainly include electrostatic interaction, reduction reaction, coordination and complexation with —NH ₂, —OH, —COOH, and “π-π” interaction with Si—O—Si. Through five times about adsorption-desorption tests, the Cr(Ⅵ) removal rate is more than 82.88%. This research presents that the ammoniated tobacco leave powder residue biochar has the potential to treat and repair acidic Cr(Ⅵ)-containing wastewater pollution.
- adsorption,
- Cr(VI),
- ammoniation,
- smoke powder,
- biochar,
- mechanism
Long Abstrsct
Innovation Points

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References(34)

References

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