纤维素导电基底及其柔性电子器件的研究进展

陶涛; 陈裙凤; 郑亦玲; 黄六莲; 陈礼辉; 欧阳新华; 李建国

doi:10.13801/j.cnki.fhclxb.20210425.001

纤维素导电基底及其柔性电子器件的研究进展

doi: 10.13801/j.cnki.fhclxb.20210425.001

陶涛^{1, 2,},
陈裙凤^{1, 2,},
郑亦玲^{1, 2,},
黄六莲^{1, 2},
陈礼辉^{1, 2},
欧阳新华^{1, 2},
李建国^{1, 2, ,}

1.
福建农林大学　材料工程学院，福州 350108
2.
植物纤维功能材料国家林业和草原局重点实验室，福州 350108

基金项目: 国家自然科学基金(31700520；31971612)；国家重点研发计划(2017YFB0307900)；福建农林大学杰出青年科研人才计划(xjq201729)；福建省自然科学基金(2018J05040)；福建农林大学校发展基金(CXZX2017040；CXZX2018007)

详细信息

通讯作者:
李建国，博士，副教授，硕士生导师，研究方向为高性能纤维素纤维制备及其应用　E-mail：jianguolicn@fafu.edu.cn

中图分类号: TN03；TQ352.7
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出版历程
- 收稿日期: 2021-01-21
- 修回日期: 2021-03-22
- 录用日期: 2021-04-19
- 网络出版日期: 2021-04-25
- 刊出日期: 2021-08-15

Research progress of cellulose conductive substrates and its flexible electronic devices

TAO Tao^{1, 2
,},
CHEN Qunfeng^{1, 2
,},
ZHENG Yiling^{1, 2
,},
HUANG Liulian^{1, 2},
CHEN Lihui^{1, 2},
OUYANG Xinhua^{1, 2},
LI Jianguo^{1, 2
, ,}

1.
School of Materials Engineering, Fujian Agriculture and Forestry University, Fuzhou 350108, China
2.
Key Laboratory of Functional Materials for Plant Fibers of the State Forestry and Grassland Administration, Fuzhou 350108, China

摘要

摘要: 纤维素是自然界中含量丰富且可再生、可降解的天然材料。本文综述了物理、化学、生物或相结合的技术对纤维素的影响作用及可制备的纤维素基元材料，例如纤维素纤维、纳米纤维素和纤维素分子。基于纤维素纤维，利用湿法造纸技术可以生产具有高孔隙率的纤维素纸张基底；基于纳米纤维素，利用真空抽滤或涂布等方式可制备具有低表面粗糙度及高透明度的纳米纤维素膜基底；基于纤维素分子，利用涂布或铸涂等方式可生产具有均一的表面形态及高透明度的再生纤维素膜基底。本文进一步分析了常用的导电材料(金属导电材料、聚合物导电材料及碳基导电材料等)及其与纤维素基底结合的方法(涂布、沉积、原位聚合、自组装等)，进而可以制备柔韧轻质的纤维素导电基底。基于高性能的纤维素导电基底可以组装柔性电子器件，在光电转化、能量储存及电磁屏蔽等领域展现了广阔的应用前景。总之，利用天然纤维素制备柔性电子器件对于扩大纤维素的应用范围、提升纤维素的利用价值及推动柔性电子器件的进一步发展具有重要意义。
- 纤维素 /
- 纤维素纸张 /
- 纳米纤维素膜 /
- 再生纤维素膜 /
- 导电材料 /
- 柔性电子器件
Abstract: Cellulose is a kind of natural material with the abundant, renewable, and degradable distinction. This article reviews the effects of physical, chemical, biological or combined technologies on cellulose, which can lead to the cellulosic materials, such as cellulose fibers, nanocellulose, and cellulose molecules. Based on cellulose fiber, the cellulose paper substrate with high porosity can be produced by wet papermaking technology. Based on nanocellulose, the nanocellulose membrane substrate with low surface roughness and high transparency can be prepared via vacuum filtration or coating. Based on cellulose molecules, the regenerated cellulose membrane substrate with uniform surface morphology and high transparency can be produced by coating or casting. The commonly used conductive materials (metal conductive materials, polymer conductive materials and carbon based conductive materials, etc.) are further investigated for manufacturing the flexible, light and conductive cellulose substrates by various preparing methods, such as coating, deposition, in-situ polymerization, or self-assembly. The high performance cellulose conductive substrates can effectively construct the flexible electronic devices, which can be applied in the fields of photoelectric conversion, energy storage and electromagnetic shielding. In conclusion, the preparation of flexible electronic devices from natural cellulose is of great significance to expand the applications of cellulose, enhances the utilization value of cellulose, and promotes the further development of flexible electronic devices.
- cellulose /
- cellulose paper /
- nanocellulose membrane /
- regenerated cellulose membrane /
- conductive material /
- flexible electronic device

HTML全文

图 1 纤维素的纤维层次及分子结构^[12-13]

Figure 1. Cellulose fiber hierarchy and molecular structure^[12-13]

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图 2 纳米纤维素膜的制备过程

Figure 2. Preparation of nanocellulose film

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图 3 再生纤维素膜的制备过程

Figure 3. Preparation of regenerated cellulose film

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图 4 纤维素在离子液体 (a)^[52]、甲基氧化吗啉(NMMO) (b)^[48]、LiCl-N,N-二甲基乙酰胺(DMAc)中 (c)^[50]和NaOH-尿素中 (d) 的溶解^[53]

Figure 4. Dissolution of cellulose in ionic liquid (a)^[52], n-methyl morpholine oxide (NMMO) (b)^[48], LiCl-N, N-dimethylacetamide (DMAc) (c)^[50]and NaOH-urea (d)^[53]

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图 5 聚合物导电材料的结构式^[78]

Figure 5. Polymer conductive material structure^[78]((a) Structural formula of polypyrrole (PPy); (b) Structural formula of polyaniline (PANI); (c) Structural formula of polythiophene (PTh))

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图 6 碳基导电材料的结构示意图^[86]

Figure 6. Schematic diagram of carbon-based conductive material^[86]

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图 7 纤维素导电基底的制备方法^[97-103]

Figure 7. Methods for preparing cellulose conductive substrate^[97-103]

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图 8 纤维素导电基底的电子器件^{[110, 129-131]}((a)~(b) 纤维素基底有机发光二极管(OLED)装置图，在平坦和弯曲状态下的J-V曲线，弯曲半径为1.5 mm；(c)~(d) 纤维素基底钙钛矿薄膜太阳能电池结构图伏安特性曲线；(e)~(f) 纤维素基底固态超级电容器的示意图及循环伏安曲线和电容曲线图；(g)~(i) 纤维素基底锂离子电池装置结构示意图、运行图、LTO(Li₄Ti₅O₁₂)阳极半电池恒流充放电曲线)

Figure 8. Electronic devices with cellulose conductive substrate^{[110, 129-131]} ((a)-(b) Cellulose-based oganic light emitting diodes (OLED) device diagram, J-V curve in flat and curved state, with a bending radius of 1.5 mm; (c)-(d) cellulose-based perovskite thin film solar cell structure diagram and its volt-ampere characteristic curve; (e)-(f) Schematic diagram and cyclic voltammetry curve, capacitance curve diagramr; (g)-(i) Schematic diagram of cellulose-based lithiumion battery device structure, operation diagram, LTO (Li₄Ti₅O₁₂) anode half battery constant current charge and discharge curve)

LCO—LiCoO₂; CNT—Carbon nanotube

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表 1 纳米纤维素的分类

Table 1. Classification of nanocellulose

Type of nanocellulose	Average size	Preparation method	Typical sources
Nanofibrillar cellulose	Diameter: 5-70 nm Length: 1-30 µm	Chemical-physical method	Wood, cotton, sugar beet, flax, algae
Nanocrystalline cellulose	Diameter: 5-70 nm Length: 100-250 nm	Chemical method	Wood, cotton, flax, wheat straw, mulberry bark, algae
Bacterial nanocellulose	Diameter: 20-100 nm	Bacterial synthesis	Low molecular weight sugars, alcohols

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