Experimental study on tensile and bending properties of sea sand ECC reinforced by BFRP bars under chloride salt erosion
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摘要: 为推广使用海洋资源,采用海砂代替硅砂制备工程水泥基复合材料(Engineering cementitious composites, ECC)。将海砂ECC与玄武岩纤维增强树脂复合材料(Basalt fiber reinforced polymer, BFRP) 筋结合,充分发挥两种材料的优点,以获得更强的耐腐蚀性能及更为优异的拉伸性能。通过单轴拉伸及四点弯曲试验,研究了不同侵蚀制度及配筋率对BFRP筋增强海砂ECC的拉伸性能及弯曲性能的影响,并与未配筋的海砂ECC作比较。结果表明,BFRP筋增强海砂ECC的极限拉应力与海砂ECC相比提升了2.46~4.92倍,极限拉应变提升了1.40~2.94倍,干湿循环作用下BFRP筋增强海砂ECC的极限荷载是海砂ECC极限荷载的3.14~4.29倍。不同侵蚀制度下,BFRP筋增强海砂ECC的最佳配筋率均为0.67%。研究的BFRP筋增强海砂ECC可为桥面无缝连接板等设计提供参考。Abstract: In order to popularize the use of marine resources, sea sand was used to prepare engineering cementitious composite (ECC) instead of silica sand. By combining sea sand ECC with basalt fiber reinforced polymer (BFRP) bars, the advantages of the two kinds of materials can be fully exploited to obtain higher corrosion resistance and better tensile properties. Through uniaxial tensile and four-point bending tests, the effects of different erosion systems and reinforcement ratio on the tensile and bending properties of BFRP reinforced sea sand ECC were studied, and compared with the sea sand ECC without BFRP reinforcement. The results show that the ultimate tensile stress of BFRP reinforced sea sand ECC is increased by 2.46-4.92 times and the ultimate tensile strain is increased by 1.40-2.94 times compared with the sea sand ECC. The ultimate load of BFRP reinforced sea sand ECC is 3.14-4.29 times of the sea sand ECC without BFRP reinforcement under the effect of dry-wetting cycling. Under different erosion systems, the optimal reinforcement ratio of BFRP reinforced sea sand ECC is 0.67%. The BFRP reinforced sea sand ECC can provide reference for the design of seamless bridge deck.
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Key words:
- Friedel’s salt /
- bending performance /
- tensile performance /
- BFRP bars /
- sea sand /
- chlorine salt erosion
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表 1 水泥、粉煤灰和偏高岭土的化学成分
Table 1. Chemical composition of cement, fly ash and metakaolin
wt% Material CaO SiO2 Al2O3 Fe2O3 MgO SO3 Na2O K2O TiO2 P2O5 Cement 63.21 18.48 6.74 3.45 3.24 3.16 0.171 0.533 0.35 0.158 Fly ash 2.58 32.54 24.76 4.92 0.397 1.17 0.523 0.589 0.717 0.251 Metakaolin 0.04 53.29 43.11 0.68 0.22 0.11 0.44 0.42 0.28 0.52 表 2 聚乙烯醇(PVA)纤维的物理力学性能
Table 2. Physical and mechanical characteristics of polyvinyl alcohol (PVA) fiber
Length/mm Diameter/μm Tensile strength/MPa Elongation/% Elastic modulus/GPa Density /(g·cm−3) 12 39 1620 7 42.8 1.3 表 3 玄武岩纤维增强树脂复合材料(BFRP)筋的物理力学性能
Table 3. Physical and mechanical characteristics of basalt fiber reinforced polymer (BFRP) bars
Diameter/
mmPeak tensile
strength/MPaElongation/
%Elastic
modulus/GPaDensity/
(g·cm−3)Longitudinal linear expansion
coefficient/(10−6℃−1)4 1099.52(44.08) 2.36(0.14) 57.28(2.18) 1.9 9.0 Notes: Data in brackets are standard deviations. 表 4 海砂工程水泥基复合材料(ECC)配合比
Table 4. Mixture proportion of sea sand engineering cementitious composite (ECC)
kg/m3 Cement Fly ash Metakaolin Silica sand Sea sand Water Fiber 278 890 56 178 267 330 26 表 5 BFRP筋增强海砂ECC复合板试件明细
Table 5. Specimen detail of BFRP reinforced sea sand ECC
Specimen ID Erosion
systemNumber of
BFRP bars4BFRP/ECC(GL, GW) Wetting-drying cycling in NaCl solution 4 3BFRP/ECC(GL, GW) 3 2BFRP/ECC(GL, GW) 2 4BFRP/ECC(JL, JW) Soaking in NaCl solution 4 3BFRP/ECC(JL, JW) 3 2BFRP/ECC(JL, JW) 2 Notes: In specimen ID, "G"—Wetting-drying cycling in NaCl solution; "J"—Soaking in NaCl solution; "L"—Uniaxial tensile test; "W"—Four-point bending test. 表 6 不同侵蚀制度及配筋率下BFRP筋增强海砂ECC复合板的单轴拉伸试验结果
Table 6. Uniaxial tensile test results of BFRP reinforced sea sand ECC under different erosion systems and reinforcement ratios
Specimen
IDFirst-crack
strength/
MPaUltimate
tensile
strength/
MPaUltimate
tensile
strain/
%2BFRP/ECC(GL) 5.04 11.33 4.92 3BFRP/ECC(GL) 9.40 15.71 6.15 4BFRP/ECC(GL) 9.11 19.35 6.99 2BFRP/ECC(JL) 5.08 13.96 5.65 3BFRP/ECC(JL) 9.38 14.44 6.27 4BFRP/ECC(JL) 9.02 16.24 8.07 表 7 不同侵蚀制度下BFRP筋增强海砂ECC复合板的四点弯曲试验结果
Table 7. Four-point bending test results of BFRP reinforced sea sand ECC under different erosion systems
Specimen ID First-crack load/N First-crack deflection/mm Ultimate load/N Ultimate deflection/mm 2BFRP/ECC(GW) 592 0.55 2212 15.47 3BFRP/ECC(GW) 557 0.45 2478 15.00 4BFRP/ECC(GW) 590 0.88 3023 15.60 2BFRP/ECC(JW) 850 0.67 3166 11.03 3BFRP/ECC(JW) 517 0.60 2256 12.97 4BFRP/ECC(JW) 297 0.30 2183 18.70 表 8 BFRP筋增强海砂ECC弯曲韧性指标
Table 8. Flexural toughness indexes of BFRP bars reinforced sea sand ECC
Specimen ID I5 I10 I20 I30 Iu 2BFRP/ECC(GW) 6 12 33 60 162 3BFRP/ECC(GW) 9 23 66 128 613 4BFRP/ECC(GW) 6 16 47 89 108 2BFRP/ECC(JW) 6 14 38 69 95 3BFRP/ECC(JW) 6 14 37 68 131 4BFRP/ECC(JW) 6 13 37 73 840 Note: I5, I10, I20, I30 and Iu—Flexural toughness indexes of BFRP bars reinforced sea sand ECC. -
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